Which solution contains the largest number of moles of chloride ions?

a.30.00 ml of 0.100m cacl2

b.10.0 ml of 0.500m bacl2

c.25.00 ml of 0.400m kcl

d.4.00 ml of 1.000m nacl

e.7.50 ml of 0.500m fecl3?

Answers

Answer 1
molarity = number of moles of solute/liters of solution
number of moles of solute = molarity x liters of solution

Part (a): 30.00 ml of 0.100m Cacl2
number of moles of CaCl2 =  0.1 x 0.03 = 3x10^-3 moles
1 mole of CaCl2 contains 2 moles of chlorine, therefore 3x10^-3 moles of CaCl2 contains 6x10^-3 moles of chlorine

Part (b): 10.0 ml of 0.500m bacl2
number of moles of BaCl2 = 0.5 x 0.01 = 5x10^-3 moles
1 mole of BaCl2 contains 2 moles of chlorine, therefore 5x10^-3 moles of BaCl2 contains 10x10^-3 moles of chlorine

Part (c): 4.00 ml of 1.000m nacl
number of moles of NaCl = 1 x 0.004 = 0.004 moles
1 mole of NaCl contains 1 mole of chlorine, therefore 4x10^-3 moles of NaCl contains 4x10^-3 moles of chlorine

Part (d): 7.50 ml of 0.500m fecl3
number of moles of FeCl3 = 0.5 x 0.0075 = 3.75x10^-3 moles
1 mole of FeCl3 contains 3 moles of chlorine, therefore 3.75x10^-3 moles of FeCl3 contains 0.01125 moles of chlorine

Based on the above calculations, the correct answer is (d)
Answer 2

The solution which contains the largest number of moles of Chlorine ions is Choice D: 7.50 ml of 0.500m fecl3.

Definition:

The molarity of a solution is simply the ratio of the number of moles of the solute to the liters of solution.

Molarity, M = number of moles of solute, (n) /liters of solution.

Number of moles of solute, n = molarity x liters of solution.

For Choice (a):

30.00 ml of 0.100m Cacl2

No. of moles of CaCl2 = 0.1 x 0.03 = 3x10-³ moles

Since, 1 mole of CaCl2 contains 2 moles of chlorine, therefore 3x10^-3 moles of CaCl2 contains 6x10^-3 moles of chlorine

For Choice (b):

10.0 ml of 0.500m BaCl2

No. of moles of BaCl2 = 0.5 x 0.01 = 5x10-³ moles

Since, 1 mole of BaCl2 contains 2 moles of chlorine, therefore 5x10-³ moles of BaCl2 contains 10x10-³ moles of chlorine

For Choice (c):

25.00ml of 0.400m KCl

No. of moles of KCl = 1 x 0.004 = 0.004 moles

Since, 1 mole of KCl contains 1 mole of chlorine, therefore 4x10-³ moles of KCl contains 4x10-³ moles of chlorine.

For Choice (d):

4.00 ml of 1.000m NaCl

No. of moles of NaCl = 1 x 0.004 = 0.004 moles

1 mole of NaCl contains 1 mole of chlorine, therefore 4x10-³ moles of NaCl contains 4x10-³ moles of chlorine.

For Choice (e):

7.50 ml of 0.500m fecl3

No. of moles of FeCl3 = 0.5 x 0.0075 = 3.75x10-³ moles

Since, 1 mole of FeCl3 contains 3 moles of chlorine, therefore 3.75x10-³ moles of FeCl3 contains 0.01125 moles of chlorine

Ultimately, The solution which contains the largest number of moles of Chlorine ions is Choice D: 7.50 ml of 0.500m FeCl3.

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